ارزیابی ویژگی‌های کاغذهای کرافت پوشش‌دهی شده با محلول‌های پروتئینی حاوی پودر عصاره چای با تکنیک لایه به لایه خود شکل گیرنده

نویسندگان
1 دانشگاه علوم کشاورزی و منابع طبیعی گرگان
2 انسیتیتوی تکنولوژی ازمیر ، دپارتمان مهندسی شیمی
چکیده
فناوری لایه به لایه خود شکل گیرنده یکی از روش­های نوین در تولید کرافت­های چندلایه با تکیه بر قرارگیری محلول پروتئینی بر بسترهای جامد است. هدف از این تحقیق تولید کرافت­های چندلایه بر پایه پلی­مرهای زیستی پروتئینی (زئین و ایزوله آب پنیر) حاوی پودر عصاره چای سبز با استفاده از فناوری لایه به لایه خود شکل گیرنده و ارزیابی خواص ضد­باکتریایی، فیزیکی- مکانیکی و رهایش ترکیبات فنولی از کرافت پوشش­دهی شده در دمای یخچالی و pHهای ۵/۴ و ۷ بود. نتایج حداقل غلظت بازدارندگی باکتریایی پودر عصاره چای سبز نشان داد که اشرشیا کلای (۵ میلی­گرم بر میلی­لیتر) در مقایسه با لیستریا مونوسیتوژنز (۱۰ میلی­گرم بر میلی­لیتر) از حساسیت بیشتری برخوردار بود. نتایج ارزیابی خواص فیزیکی کرافت­ها نشان داد که ضخامت، گراماژ و دانسیته حجمی طی پوشش­دهی افزایش یافت. هم­چنین قرارگیری زئین در لایه خارجی سبب کاهش نفوذپذیری نسبت به بخار آب و افزایش مقاومت در برابر عبور هوا گردید. ارزیابی رهایش ترکیبات فنولی از بستر کرافت­های پوشش­دهی شده نشان داد که سرعت رهایش در مدل غذایی اسیدی بیش از مدل خنثی بود. هم­چنین رهایش ترکیبات فنولی از کرافت­های پوشش­دهی شده زئین به­عنوان لایه خارجی در مقایسه با ایزوله­پروتئین­آب­پنیر در روزهای نخست بیشتر و در زمان طولانی­تری ادامه داشت. کاهش اندیس لگاریتمی کرافت پوشش­دهی شده با زئین فعال دولایه علیه اشرشیا کلای و لیستریا مونوسیتوژنز به­ترتیب ۲۵/۰ و۰۶/۰ بود. بر اساس نتایج به­دست آمده از این تحقیق کرافت پوشش­دهی شده با دولایه زئین فعال برای بسته­بندی مواد غذایی به­عنوان حامل ترکیبات فنولی توصیه می­گردد
کلیدواژه‌ها

موضوعات


عنوان مقاله English

Characteristics of kraft papers coated with protein solutions containing tea extract powder with a layer-by-layer technique

نویسندگان English

Mahboobeh Kashiri 1
Hassan Asadi 1
Yahya Maghsoudlou 1
Habiballah Mirzaei 1
Sacide Alsoy Altinkaya 2
1 Agricultural Sciences & Natural Resources University of Gorgan,
2 Izmir Institute of Technology · Department of Chemical Engineering
چکیده English

Layer by layer self - assembly technique is one of the newest methods to produce multilayer films relying on the placement of the liquid layers on solid substance. The purpose of this studies is to manufacture multilayer kraft based on protein biopolymers (zein and whey isolated protein) containing of green tea phenolic compounds by utilizing layer by layer self - assembly technique and evaluation antibacterial, physical-mechanical properties and release of phenolic compounds from coated kraft at refrigerator temperature in pH of 4.5 and 7. The minimum inhibitory concentration of green tea powder demonstrates that Escherichia coli (5mg/ml) compared to Listeria monocytogenes (10mg/ml) is more sensitive. The results of physical properties of krafts coated paper showed that thickness, grammage and bulk density increased by coating process. Also, the presence of zein in outer layer caused a significant reduction in WVP and increased air resistance. Evaluation of phenolic compounds release from coated krafts demonstrated that release rate in acidic food stimulant was more than the neutral stimulants. Also, release content of kraft paper with zein as outer layers respect to whey isolated protein was higher in the first days and continued in a longer time. Log reduction value of coated Kraft with active bilayer zein against Escherichia coli and Listeria monocytogenes was 0.25 and 0.06 respectively. According to the results of this study, active zein bilayer kraft is recommended as a carrier of phenolic compounds for the packaging of food products

کلیدواژه‌ها English

Layer by layer self - assembly technique
Zein
Whey isolate protein
Kraft
Green tea extract powder
[1] Anonymous, 2015, Euromonitor Off trade and retail plastics packaging. International Energy Agency, World Energy, www.coursehero.com.
[2] Shan, G., Surampalli, R. Y., Tyagi, R.D .and Zhang, T. C. 2009. Nanomaterials for environmental burden reduction, waste treatment, & nonpoint source pollution control. Frontiers Environmental Science & Engineering inChina, 3(3): 249–264.
[3] Cheng, S.Y., Wang, B.J. and Weng, Y.M. 2015. Antioxidant and antimicrobial edible zein/chitosan composite films fabricated by incorporation of phenolic compounds and dicarboxylic acids. LWT-Food Science Technology, 63(1): 115-121.
[4] Panyam, J. and Labhasetwar, V. 2003. Biodegradable nanoparticles for drug and gene delivery to cells and tissue. Advanced Drug Delivery Elsevier, 55: 329–347.
[5] Balan, T., Guezennec, C., Nicu, R., Ciolacu, F. and Bobu, E. 2015. Improving barrier & strength properties of paper by multi-layer coating with bio-based additives. Cellulose Chemistry and Technology, 49: 607-615.
[6] Borges, J. and Mano, J.F. 2014. Molecular interactions driving the layer-by-layer assemble of multilayers. Chemical Review, 114(18): 8883-8942.
[7] Barroti, S.L.B. 1998. Celulose e papel-technologia de fabricacao do papel. Instituyo de Pesquisas Technological do Estado de Sao Paulo, 848-849.
[8] Wang, Sh.and Jing, Y. 2016. Effects of chitosan coating layer on the surface properties & barrier properties of Kraft paper. Bio Resources, 11(1): 1868-1881.
[9] Unalan, L.U., Arcan, L., Korel, F. and Yemenicioglu, A. 2013. Application of active zein based film with controled release properties to control Listeria monocytogenes growth & lipid oxidation in fresh kashar cheese. Innovative Food Science & Emerging Technologies, 20: 208-214.
[10] Rastogi, V., & Samyn, P. (2015). Bio-based coatings for paper applications. Coatings, 5(4), 887-930.
[11] Arcan, I.,& Yemeniciuglu, A. (2011). Incorporating phenolic compounds opens a new perspective to use zein films as flexible bioactive packaging materials. Food Research International, 44(2): 550-556. [12] Ozer, B.B.P., Uz, M., Oymacy, P. and Altinkaya, S. 2016 Development of a novel strategy for controlled release of lysozyme from whey protein isolate based active food packaging film. Food Hydrocolloids, 61: 877-886.
[12] Ozer, B. B. P., Uz, M., Oymacy, P., & Altinkaya, S. (2016). Development of a novel strategy for controlled release of lysozyme from whey protein isolate based active food packaging film. Food Hydrocolloids, 61: 877-886.
[13] Lorenzo, J. M., & Munekata, P. E. S. (2016). Phenolic compounds of green tea: Health & technological application in food. Asian Pacific of Tropical Biomedicine, 6(8): 709-719.
[14] ISO 2758: 2014: Paper. Determination of bursting strength. ISO, Geneva, Switzerland.
[15] ASTM. (1996). Standard test methods for tensile properties of thin plastic sheeting, D882e91 Philadelphia, PA: American Society for Testing & Material.
[16] ISO 5636-5: 2013: Paper & board determination of Air Permeable (medium range). Part 5: Gurley Method. ISO, Geneva, Switzerland.
[17] Singleton, V.L. and Rossi, J.A. 1965. Colorimetry of total phenolics with phosphomolybdic-phosphotungstic acid reagent. American Journal of Enology and Viticulture, 16(3): 144-158.
[18] Hashemi, A., Shams, S., Barati, M. and Samedani, A. 2011. Antibacterial effects of methanolicextract of Zatariamultiflora, Myrtuscommunis & Peganumharmala on Pseudomonas aeruginosa producing ESBL. Ark Medical University Journal, 14(57): 104-112.
[19] Muriel-Galet, V., Lopez-Carballo, G., Hernandez-Munoz, P. and Gavara, R. 2014. Characterization of ethylene-vinyl alcohol copolymer containing laurilarginate (LAE) as material for activeantimicrobial food packaging. Food Packaging and Shelf Life, 1(1): 10-18.
[20] Brodnjak, U.V. 2017. Influence of ultrasonic treatment on properties of bio-based coated paper. Progress in Organic Coatings, (103): 93-100.
[21] Battisti, R., Fronza, N., Júnior, Á.V., da Silveira, S.M., Damas, M.S.P. and Quadri, M.G.N. 2017. Gelatin-coated paper with antimicrobial & antioxidant effect for beef packaging. Food Packaging and Shelf Life, (11): 115-124.
[22] Sangaj, N.S. and Malshe, V.C. 2004. Permeability of polymer in protective organic coatings-A review. Progress in Organic Coating, (50): 28-39.
[23] Khwaldia, K., Arab‐Tehrany, E. and Desobry, S., 2010. Biopolymer coatings on paper packaging materials. Comprehensive Reviews in Food Science and Food Safety, 9: 82-91.
[24] Kamal, M., Jinnah, I. and Utracki, L. 1984. Permeability of oxygen and water vapor through polyethylene/polyamide films. Polymer Engineering and Science, 24: 1337-1347.
[25] Krochta, J.M. and Johnston, D.M. 1997. Edible & biodegradable polymer films: challenges & opportunities. Food Technology, 51(2): 61-74.
[26] Aloui, H., Khwaldia, K., Slama, M.B. and Hamdi, M. 2011 Effect of glycerol and coating weight on functional properties of biopolymer-coated paper. Carbohydrate Polymers, 986: 1063-1072.
[27] Tihminlioglu, F., Atik, İ.D. and Özen, B. 2010. Water vapor and oxygen-barrier performance of corn–zein coated poly propylene films. Journal of Food Engineering, 96: 342-347.
[28] Wang, Y. and Padua, G.W. 2010. Formation of zeinmicrophases in etanol-water. Langmuir, 26(15): 12897-12901.
[29] Lai, H.M., Padua, G. W. and Wei, L. Sh. 1997. Properties & microstructure of zein sheets plasticized with palmitic and stearic acids. Cereal Chemistry, 74(6): 771-775.
[30] Oymaci, P. and Altinkaya, S.A. 2016. Improvement of barrier & mechanical properties of whey protein isolate based food packaging films by incorporation of zein nanoparticles as a novel bionanocomposite. Food Hydrocolloids, 54: 1-9.
[31] Gällstedt, M., Brottman, A. and Hedenqvist, M.S. 2005. Packaging‐related properties of protein‐and chitosan‐coated paper. Packaging Technology and Science: An International Journal, 18: 161-170.
[32] Han, J. and Krochta, J. 2001 Physical properties and oil absorption of whey‐protein‐coated paper. Journal of Food Science, 66: 294-299.
[33] Khwaldia, K., Linder, M., Banon, S. and Desobry, S. 2005. Combined effects of mica, camauba wax, glycerol and sodium caseinate concentration on water vapor barrier & mechanical properties of coated paper. Journal of Food Science, 70: 192-7.
[34] Ramos, M., Valdes, A., Mellinas, A.C. and Garrigos, M.C. 2015. New trends in beverage packaging system: A review. Beverages, 1: 248-272.
[35] Samahy, M.A., Mohamed, A.A., Rehim, M.H. A. and Mohram, M.E. 2017. Synthesis of hybrid paper sheets with enhanced air barrier & antimicrobial properties for food packaging. Carbohydrate Polymers, 168: 212-219.
[36] Li, Y., Li, J., Xia, Q., Zhang, B., Wang, Q. and Huang, Q. 2012. Understanding the dissolution of α-zein in aqueous ethanol and acetic asid solutions. The Journal of Physical Chemistry, 116(39): 12057-12064.
[37] Kashiri, M. 2015. Effect of food stimulants & temperature condition on releasing of Lauroyl-L-arginine ethyl ester mono hydrochloride & antimicrobial properties of zein based films. Electronic Journal of Food Processing and Preservation, 7(2): 61-76.
[38] Boyaci, D., Korel, F. and Yemenicioglu, A. 2016. Development of activate at home type edible antimicrobial films: An example pH triggering mechanism formed for smoked salmon slices using lysozyme in whey protein film. Food Hydrocolloids, 60: 170-178.
[39] Livney, Y. D. 2010. Milk proteins as vehicles for bioactives. Current Opinion in Colloid Interface Science, 15(1–2): 73–83.
[40] Haratifar, S. and Correding, M. 2014. Interaction between tea catechins & casein micelles & their impact on renneting functionality. Food Chemistry, 143: 27-32.
[41] Munin, A. and Edwards-Lévy, F. 2011. Encapsulation of natural polyphenolic compounds: A review. Pharmaceutics, 3(4): 793–829.
[42] Friedman, M. 2007. Overview of antibacterial, antitoxin, antiviral, & antifungal activities of tea flavonoids and teas. Molecular Nutrition & Food Research, 51: 116-134.
[43] Giménez, B., de Lacey, A.L., Pérez-Santín, E., López-Caballero, M. and Montero, P. 2013. Release of active compounds from agar and agar–gelatin films with green tea extract. Food Hydrocolloids 30: 264-271.
[44] Chung, J.H., Han, J.H., Hwang, E.J., Seo, J.Y., Cho, K.H. and Kim, K.H. 2003. Dual mechanisms of green tea extract (EGCG)-induced cell survival in human epidermal keratinocytes. The Journal of the Federation of American Societies for Experimental Biology, 17: 1913–1915.
[45] Nibir, Y.M., Sumit, A.F., Akh, A.A., Ahsan, N. and Hossain, M.S. 2017. Comparative assessment of total polyphenols, antioxidant and antimicrobial activity of different tea varieties of Bangladesh. Asian Pacific Journal of Tropical Biomedicine 7: 352-357.
[46] Chan, E.W., Soh, E.Y., Tie, P.P. and Law, Y.P. 2011. Antioxidant and antibacterial properties of green, black, and herbal teas of Camellia sinensis. Pharmacognosy Research, 3: 266.