مجله علوم و صنایع غذایی ایران

مجله علوم و صنایع غذایی ایران

Development of Sustainable Active Biocomposite Films from Rice Flour, Carrageenan, and Date Pit Extract for Enhanced Food Packaging and Shelf Life Extension of Perishable Dairy Products

نوع مقاله : مقاله پژوهشی

نویسندگان
1 Department of Food Science / College of Agriculture
2 2Department of Food Science / College of Agriculture
10.48311/fsct.2026.122305.83342
چکیده
This study developed novel biocomposite active films from rice flour (a low cost agricultural by product) and carrageenan, reinforced with polyphenol rich date pit extract (DPE) at 0, 1, 2, and 3% (w/w), using glycerol as a plasticizer and the solvent casting method. The optimal formulation (T2, 2% DPE) significantly improved mechanical performance, increasing tensile strength by approximately 44% to 25.8 MPa, while achieving the lowest water vapor permeability (6.47 × 10⁻¹¹ g/m·s·Pa). FTIR and SEM analyses confirmed robust hydrogen bonding and homogeneous microstructural distribution at 2% DPE, whereas 3% loading caused molecular aggregation and phase separation. The active films exhibited a substantial increase in total phenolic content and radical scavenging activity (DPPH and ABTS), maintaining exceptional biochemical stability over 12 weeks of storage. The soil burial test verified rapid biodegradation (95 100% within 30 days), confirming environmental sustainability. Preliminary application on soft cheese demonstrated that T2 and T3 films maintained total viable counts below the spoilage threshold (7 log CFU/g) throughout 21 days of refrigerated storage, extending shelf life by 2 4 days compared to control films. From an industrial perspective, these films offer multiple benefits: (i) reducing dependence on synthetic plastics through the use of renewable agricultural by products; (ii) extending the shelf life of perishable dairy products through controlled release of bioactive phenolic compounds; (iii) reducing food waste and associated economic losses; and (iv) meeting growing consumer demand for clean label, environmentally sustainable packaging
کلیدواژه‌ها
موضوعات

[1]       Dirpan, A., Ainani, A.F., & Djalal, M. (2023). A review on biopolymer‑based biodegradable film for food packaging: Trends over the last decade and future research. Polymers, 15(13), 2781.
[2]       Cai, J., Hafeez, M.A., Wang, Q., Farooq, S., Huang, Q., Tian, W., & Xiao, J. (2022). Biopolymer‑based functional films for packaging applications: A review. Frontiers in Nutrition, 9, 1000116.
[3]       Kumar, A., Kumar, A., Wei, S., Chopra, S., Rudra, S.G., & Rabbani, A. (2025). Biodegradable and smart packaging films for food quality and safety: A review. Applied Food Research, 5(2), 101491.
[4]       Dias, A.B., Müller, C.M.O., Larotonda, F.D.S., & Laurindo, J.B. (2010). Biodegradable films based on rice starch and rice flour. Journal of Cereal Science, 51(2), 213‑219.
[5]       Thakur, R., Saberi, B., Pristijono, P., Golding, J., Stathopoulos, C., Scarlett, C., Bowyer, M., & Vuong, Q. (2016). Characterization of rice starch‑κ‑carrageenan biodegradable edible film: Effect of stearic acid on the film properties. International Journal of Biological Macromolecules, 93, 952‑960.
[6]       Sandhu, K.S., Sharma, L., Kaur, M., & Kaur, R. (2020). Physical, structural and thermal properties of composite edible films prepared from pearl millet starch and carrageenan gum: Process optimization using response surface methodology. International Journal of Biological Macromolecules, 143, 704‑713.
[7]       Periyasamy, T., Asrafali, S.P., & Lee, J. (2025). Recent advances in functional biopolymer films with antimicrobial and antioxidant properties for enhanced food packaging. Polymers, 17(9), 1257.
[8]       Sousa, R., Silva, J.M., Verano‑Naranjo, L., Cejudo‑Bastante, C., Facchinatto, W.M., Almeida, A., Silvestre, A.J.D., Freire, C.S.R., & Vilela, C. (2025). Functional biopolymeric materials for active food packaging: The case of monolayer films of thermoplastic starch and olive leaf extract. Frontiers in Bioengineering and Biotechnology, 13, 1672740.
[9]       Khwaldia, K., Attia, H., & Besbes, S. (2023). Date palm (Phoenix dactylifera L.) by‑products: A review of their potential for food packaging applications. Food Packaging and Shelf Life, 36, 101052.
[10]    Abdillah, A.A., & Charles, A.L. (2021). Characterization of a natural biodegradable edible film obtained from arrowroot starch and iota‑carrageenan and application in food packaging. International Journal of Biological Macromolecules, 191, 618‑626.
[11]    Marcet, I. (2023). The characterization of biodegradable films and food packaging. Membranes, 13(10), 826.
[12]    Ainsworth, E.A., & Gillespie, K.M. (2007). Estimation of total phenolic content and other oxidation substrates in plant tissues using Folin‑Ciocalteu reagent. Nature Protocols, 2(4), 875‑877.
[13]    Re, R., Pellegrini, N., Proteggente, A., Pannala, A., Yang, M., & Rice‑Evans, C. (1999). Antioxidant activity applying an improved ABTS radical cation decolorization assay. Free Radical Biology and Medicine, 26(9‑10), 1231‑1237.
[14]    Dmitrenko, M., Kuzminova, A., Cherian, R.M., Joshy, K.S., Pasquini, D., John, M.J., Hato, M.J., Thomas, S., & Penkova, A. (2023). Edible carrageenan films reinforced with starch and nanocellulose: Development and characterization. Sustainability, 15(22), 15817.