بهبود پایداری اکسایشی روغن آفتابگردان با استفاده از روغن پوست بنه در مقادیر بسیار کم

نویسندگان
1 گروه علوم و صنایع غذایی، دانشکده کشاورزی، دانشگاه جهرم، جهرم، فارس، ایران
2 گروه علوم و صنایع غذایی، دانشکده کشاورزی، دانشگاه جهرم، جهرم، فارس، ایران.
3 کارمند آزمایشگاه غذا و دارو دانشگاه علوم پزشکی جهرم
چکیده
در تحقیق حاضر، اثر مقادیر مختلف روغن پوست بنه (05/0 تا 5/0 درصد) بر پایداری اکسایشی روغن آفتابگردان تصفیه­شده طی 8 ساعت فرایند حرارتی در 170 درجه­سانتیگراد بررسی شد که از آنتی­اکسیدان سنتزی TBHQ به میزان 100 پی­پی­ام جهت مقایسه استفاده گردید. بررسی نتایج آزمونهای مختلف پایداری اکسایشی (عدد پراکسید، اندیس آنیزیدین، اندیس توتوکس، عدد ­دی­ان­مزدوج و عدد اسیدی) نشان­داد که استفاده از روغن پوست بنه باعث بهبود پایداری اکسایشی روغن آفتابگردان شد. بهترین شرایط پایداری اکسایشی در روغن آفتابگردان حاوی 05/0درصد روغن پوست بنه مشاهده شد و بعد از ان نمونه روغن حاوی 1/0 درصد روغن پوست بنه قرار داشت که هر دو دارای اثر آنتی­اکسیدانی برتر از TBHQ بودند. به منظور تفسیر بهتر نتایج آزمونهای پایداری اکسایشی، تغییرات ترکیبات توکوفرولی و پلی­فنلی به عنوان دو ترکیبب آنتی­اکسیدانی شاخص طی فرایند حرارتی بررسی شد. نتایج نشان داد بین تغییرات این ترکیبات و آزمونهای پایداری اکسایشی ارتباط وجود ندارد. نمونه حاوی TBHQ دارای بیشترین اثر حفاظتی بر ترکیبات آنتی­اکسیدانی بود که به علت ایجاد حالت پراکسیدانی ناشی از افزایش آنتی­اکسیدانها، باعث کاهش پایداری اکسایشی روغن آفتابگردان شد. همچنین بررسی تغییرات فعالیت آنتی­اکسیدانی طی فرایند حرارتی به کمک دو آزمون قدرت مهارکنندگی رادیکال آزاد و رنسیمت نیز نشان داد که نمونه روغن آفتابگردان حاوی 05/0 درصد روغن پوست بنه بهترین شرایط را داشت که با نتایج آزمونهای پایداری اکسایشی همخوانی داشت.. ارزش این نتایج زمانی مشخص ­می­شود که روغن پوست بنه در مقایسه با TBHQ اصلا خالص نبود.
کلیدواژه‌ها

موضوعات


عنوان مقاله English

Improving the oxidative stability of sunflower oil by using the oil from the Baneh skin in very small amounts

نویسندگان English

Javad Tavakoli 1
Negar Razmkhah 2
Masoomeh Ranjbar 3
1 Food and Drug Laboratory, Jahrom University of Medical Sciences, Jahrom, Iran
2 Food and Drug Laboratory, Jahrom University of Medical Sciences, Jahrom, Iran
3 Jahrom University of Medical Sciences
چکیده English

In the present study, the effect of different amounts of Baneh skin oil (0.05% to 0.5%) on the oxidative stability of refined sunflower oil during 8 hours of thermal process at 170 °C was investigated, which was 100 ppm of synthetic antioxidant TBHQ. used for comparison. Evaluating the results of various oxidative stability tests (peroxide value, anisidine value, totox value, Conjugated diene value and acid value) showed that the use of Baneh skin oil improved the oxidative stability of sunflower oil. The best conditions of oxidative stability were observed in sunflower oil containing 0.05% of Baneh skin oil, followed by the oil sample containing 0.1% of Baneh skin oil, both of which had a superior antioxidant effect than TBHQ. In order to better interpret the results of oxidative stability tests, the changes of tocopherol and polyphenolic compounds as two indicator antioxidant compounds were investigated during the thermal process. The results showed that there is no relationship between the changes of these compounds and oxidative stability tests. The sample containing TBHQ had the greatest protective effect on antioxidant compounds, which due to the creation of a peroxidative state caused by the increase of antioxidants, it decreased the oxidative stability of sunflower oil. Also, the investigation of changes in antioxidant activity during the thermal process with the help of two DPPH radical scavenging and Rancimet tests also showed that the sunflower oil sample containing 0.05% of Baneh skin oil had the best conditions, which was consistent with the results of oxidative stability tests. The results of the present research are very important because the oil of the Baneh skin oil was not pure at all compared to TBHQ.

کلیدواژه‌ها English

Natural antioxidant
Oxidation
Edible Oil
synthetic antioxidant
Antioxidant activity
[1] Mota, M.F.S., Waktola, H.D., Nolvachai, Y., Marriott, P.J., 2021. Gas chromatography mass spectrometry for characterisation, assessment of quality and authentication of seed and vegetable oils. TrAC Trends in analytical chemistry, 138, 116238.
[2] Schaich, K.M., 2005. Lipid Oxidation: Theoretical Aspects. In: Shahidi F (ed) Bailey’s industrial oil and fat products. 6rd edn. Wiley, New Jersey, pp 268-355.
[3] Sosa, V., Moliné, T., Somoza, R., Paciucci, R., Kondoh, H., Leonart, M.E., 2013. Oxidative Stress, and Cancer: An Overview. Journal of Ageing Research Reviews, 12, 376–390.
[4] Tavakoli, J. & Sorbi, N., 2018. Fortification of refined soybean oil by hull oil of Kolkhoung (Wild pistachio in Iran): Improving thermal stability during frying process. International Journal of Food Properties, 20, 2990-3003.
[5] Sharayei, P., Farhoosh, R., Poorazarang, H., Haddad Khodaparast, M.H., 2011. Effect of Bene Kernel Oil on the Frying Stability of Canola Oil. American Oil Chemists’ Society,88, 648-654.
[6] Sharayei, P., Farhoosh, R., Poorazarang, H., Haddad Khodaparast, M.H., 2011. Improvement of canola oil frying stability by Bene kernel oil’s unsaponifiable matter. American Oil Chemists’ Society, 88: 993-1000.
[7] Tavakoli, J ,. Hamedani ,F ,. Haddad Khodaparast, M.H ,.(2016). Investigating Chemical Properties and Oxidative Stability of Kernel Oil from Pistacia khinjuk Growing Wild in Iran. American Oil Chemists' Society, 93: 681–687.
[8] Sharif, A., Farhoosh, R., Haddad Khodaparast, M. H., Tavassoli-Kafrani, M.H., 2009. Antioxidant activity of Bene hull oil compared with sesame and rice bran oils during the frying process of sunflower oil. Food Liopds, 16, 394-406.
[9] Farhoosh, R., Haddad Khodaparast, M. H., Sharif, A., 2009. Bene hull oil as a highly stable and antioxidative vegetable oil. European Journal of Lipid Science and Technology, 111, 1259–1265.
[10] Farhoosh, R., Tavassoli-Kafrani, M.H., Sharif, A., 2011. Antioxidant activity of sesame, rice bran and bene hull oils and their unsaponifiable matters. European Journal of Lipid Science and Technology, 113, 506–512.
[11] Tavakolli, J., Sedaghat, N., Mousavi Khaneghah, A., 2019. Effects of packaging and storage conditions on Iranian wild pistachio kernels and assessment of oxidative stability of edible extracted oil. Food Processing and Preservation, 43, 1-10.
[12] Farhoosh, R., & Pazhouhanmehr, S., 2009. Relative contribution of compositional parameters to the primary and secondary oxidation of canola oil. Food Chemistry, 114(3), 1002–1006.
[13] Tavakoli, J., Emadi, T., Hashemi, S. M. B., Mousavi Khaneghah, A., Munekata, P. E. S., Lorenzo, J. M., Brnčić, M., Barba, F. J., 2018. Chemical properties and oxidative stability of Arjan (Amygdalus reuteri) kernel oil as emerging edible oil. Food Research International, 107, 378-384.
[14] Roshanpour, S., Tavakoli, J., Beigmohammadi, F., Alaei, Sh., 2021. Improving antioxidant effect of phenolic extract of Mentha piperita using nanoencapsulation process. Journal of Food Measurement and Characterization, 15(1), 23–32.
[15] Lozano, Y., Mayer, C. D., Bannon, C., Gaydou, E. M., 1993. Unsaponifiable matter, total sterol and tocopherol contents of avocado oil varieties. Journal of the American Oil Chemists' Society, 70, 561–565.
[16] Sfahlan, A. J., Mahmoodzadeh, A., Hasanzadeh, A., Heidari, R., Jamei, R., 2009. Antioxidants and antiradicals in almond hull and shell (Amygdalus communis L.) as a function of genotype. Food Chemistry, 115(2), 529-533.
[17] Yim, H. S., Chye, F. Y., Koo, S. M., Matanjun, P., How, S. E., Ho, C. W., 2012. Optimization of extraction time and temperature for antioxidant activity of edible wild mushroom, Pleurotus porrigens. Food & Bioproducts Processing, 90: 235-242.
[18] Tavakoli, J., Hajpour Soq, K. H., Yousefi, A. R., Estakhr, P., Dalvi, M., Mousavi Khaneghah, A., 2019. Antioxidant activity of Pistacia atlantica var mutica kernel oil and it’s unsaponifiable matters. Journal of Food Science & Technology, 56: 5336–5345.
[19] Gunstone, F. D., 2005. Vegetable Oils. In: Shahidi F (ed) Bailey’s industrial oil and fat products. 6rd edn. Wiley, New Jersey, pp 1-55.
[20] Liu, R., Liu, R., Shi, L., Zhang, Z., Zhang, T., Lu, M., Chang, M., Jin, X.,Wang, X., 2019. Effect of refining process on physicochemical parameters, chemical compositions and in vitro antioxidant activities of rice bran oil. LWT-Food Science and Technology, 109, 26–32.
[21] Tavakoli, J., Brewer, M.S., Zarei Jelyani, A., Estakhr, P., 2017. Oxidative stability of olive oil during the thermal process: Effect of Pistacia khinjuk fruit oil. International Journal of Food Properties, 20, 3256-3265.
[22] Frankel, E.N. 2005. Lipid Oxidation (2ed). The Oily Press LTD
[23] Tavakoli, J., Estakhr, P., Zarei Jelyani, A., 2017. Effect of unsaponifiable matter extracted from Pistacia khinjuk fruit oil on the oxidative stability of olive oil. Journal of Food Science and Technology, 54,2980–2988.
[24] Veronezi, C.M., Jorge, N., 2018. Effect of Carica papaya and Cucumis melo seed oils on the soybean oil stability. Food Science and Biotechnology. 27, 1031–1040.
[25] Kowalski, B., Ratusz, K., Kowalska, D., Bekas, W., 2004. Determination of the oxidative stability of vegetable oils by differential scanning calorimetry and Rancimat measurements. European Journal of Lipid Science and Technology, 106, 165–169.
[26] Shahidi, F. & Zhong, Y., 2005. Lipid Oxidation: Measurement Methods. In: Shahidi F (ed) Bailey’s industrial oil and fat products. 6rd edn. Wiley, New Jersey, pp 370-373.